This synthetic route represents an alternative to the long

The synthesis of a range of trans RuCl(CCC6H4R)(dppe)2 complexes, in which R is either an electron donor (Me, OMe, C5H11) or acceptor (NO2, CO2Me), from the five coordinate complex [RuCl(dppe)2]OTf is described. This synthetic route represents an alternative to the long standing methods based on cis RuCl2(dppe)2. Improved synthetic routes to both [RuCl(dppe)2]OTf and cis RuCl2(dppe)2 are also given.

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