6) variation was found in the Raman region and the transition
The work presented in this thesis describes the development and application of strategies to evaluate the influence of extreme confinement within narrow single walled carbon nanotubes (SWNT) on the pathways of preparative chemical reactions. Methodologies to reduce carbon nanotube length were critically assessed in order to aid the access and egress of reactants and products to and from the SWNT internal channel during confined reactions. A reliable procedure for the encapsulation of organic molecules within carbon nanotubes was developed utilising a novel fractional distillation procedure which exploits the effect of nanoscale confinement on the phase behaviour of liquids.
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